23178
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23178
Fluka
1-Chloroethyl chloroformate
purum, ≥98.0% (GC)
| Synonym: | ACE-Cl |
| CAS Number: | 50893-53-3 |
| Linear Formula: | CH3CHClOCOCl |
| Molecular Weight: | 142.97 |
| Beilstein Registry Number: | 1747601 |
| EC Number: | 256-834-2 |
| MDL number: | MFCD00000647 |
| PubChem Substance ID: | 24853857 |
Description
| Other Notes | Reagent for the selective N-dealkylation of tertiary amines1; Reagent for the synthesis of alkyl 1-chloroethyl carbonates, useful in the synthesis of drugs2,3,4 |
Properties
| vapor pressure | 3.25 psi ( 20 °C) |
| grade | purum |
| assay | ≥98.0% (GC) |
| refractive index | n |
| n | |
| bp | 118-119 °C(lit.) |
| density | 1.325 g/mL at 25 °C(lit.) |
| storage temp. | 2-8°C |
Safety
| Personal Protective Equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | T |
| Risk Statements | 10-22-23-34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN2742 6.1/PG 2 |
| WGK Germany | 3 |
| Flash Point(F) | 104.9 °F |
| Flash Point(C) | 40.5 °C |
References
| Cited Reference | 1. R.A. Olofson, D.E. Abbott J. Org. Chem. 49, 2795, (1984) |
| 2. R. Heymes, D. Pronine Fr. Demande 2.532.313 | |
| 3. K. Takanohashi et al. Eur. Pat. 128.028 | |
| 4. J. Alexander Eur. Pat. 167.451 | |
| Beilstein | Beil. 3,H,12 |
| Fieser | Fieser 12,112 / Fieser 15,83 |
| reference | Corp MSDS 1 (1), 776:A / FT-IR 2 (1), 1237:A / FT-NMR 1 (1), 1202:A / RegBook 1 (1), 859:E / Structure Index 1, 132:C:4 |
